Petroleum was first published in 1556 by the German mineralogist Georg Bauer, known as Georgius Agricola.) is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds.
Composition>>
The proportion of hydrocarbons in the mixture is highly variable and ranges from as much as 97% by weight in the lighter oils to as little as 50% in the heavier oils and bitumens.
The hydrocarbons in crude oil are mostly alkanes, cycloalkanes and various aromatic hydrocarbons while the other organic compounds contain nitrogen, oxygen and sulfur, and trace amounts of metals such as iron, nickel, copper and vanadium. The exact molecular composition varies widely from formation to formation but the proportion of chemical elements vary over fairly narrow limits as follows:
Carbon
83-87%
Hydrogen
10-14%
Nitrogen
0.1-2%
Oxygen
0.1-1.5%
Sulfur
0.5-6%
Metals
<1000>>>
Geologists view crude oil and natural gas as the product of compression and heating of ancient organic materials (i.e. kerogen) over geological time. Formation of petroleum occurs from hydrocarbon pyrolysis, in a variety of mostly endothermic reactions at high temperature and/or pressure. Today's oil formed from the preserved remains of prehistoric zooplankton and algae, which had settled to a sea or lake bottom in large quantities under anoxic conditions (the remains of prehistoric terrestrial plants, on the other hand, tended to form coal). Over geological time the organic matter mixed with mud, and was buried under heavy layers of sediment resulting in high levels of heat and pressure (known as diagenesis). This caused the organic matter to chemically change, first into a waxy material known as kerogen which is found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons in a process known as catagenesis.
Geologists often refer to the temperature range in which oil forms as an "oil window"—below the minimum temperature oil remains trapped in the form of kerogen, and above the maximum temperature the oil is converted to natural gas through the process of thermal cracking. Although this temperature range is found at different depths below the surface throughout the world, a typical depth for the oil window is 4–6 km. Sometimes, oil which is formed at extreme depths may migrate and become trapped at much shallower depths than where it was formed. The Athabasca Oil Sands is one example of this.
Petroleum industry>>>
The petroleum industry is involved in the global processes of exploration, extraction, refining, transporting (often with oil tankers and pipelines), and marketing petroleum products. The largest volume products of the industry are fuel oil and gasoline (petrol). Petroleum is also the raw material for many chemical products, including pharmaceuticals, solvents, fertilizers, pesticides, and plastics. The industry is usually divided into three major components: upstream, midstream and downstream. Midstream operations are usually included in the downstream category.
Petroleum is vital to many industries, and is of importance to the maintenance of industrialized civilization itself, and thus is critical concern to many nations. Oil accounts for a large percentage of the world’s energy consumption, ranging from a low of 32% for Europe and Asia, up to a high of 53% for the Middle East. Other geographic regions’ consumption patterns are as follows: South and Central America (44%), Africa (41%), and North America (40%). The world at large consumes 30 billion barrels (4.8 km³) of oil per year, and the top oil consumers largely consist of developed nations. In fact, 24% of the oil consumed in 2004 went to the United States alone.The production, distribution, refining, and retailing of petroleum taken as a whole represent the single largest industry in terms of dollar value on earth.
Uses>>>
The chemical structure of petroleum is composed of hydrocarbon chains of different lengths. Because of this, petroleum may be taken to oil refineries and the hydrocarbon chemicals separated by distillation and treated by other chemical processes, to be used for a variety of purposes. See Petroleum products.
Fuels
The most common distillations of petroleum are as various fuels. These include:
Ethane and other short-chain alkanes
Diesel fuel (petrodiesel)
Fuel oils
Gasoline
Jet fuel
Kerosene
Liquefied petroleum gas (LPG)
Natural gas
Other derivatives
Certain types of resultant hydrocarbons may be mixed with other non-hydrocarbons, to create other end products:
Alkenes (olefins) which can be manufactured into plastics or other compounds
Lubricants (produces light machine oils, motor oils, and greases, adding viscosity stabilizers as required).
Wax, used in the packaging of frozen foods, among others.
Sulfur or Sulfuric acid. These are a useful industrial materials. Sulfuric acid is usually prepared as the acid precursor oleum, a byproduct of sulfur removal from fuels.
Bulk tar.
Asphalt
Petroleum coke, used in speciality carbon products or as solid fuel.
Paraffin wax
Aromatic petrochemicals to be used as precursors in other chemical
production.
Consumption statistics
Global fossil carbon emissions, an indicator of consumption, for 1800 - 2004. Total is black, Oil is in blue.
World energy consumption, 1980 - 2030. Source: International Energy Outlook 2006.
Environmental effects
Diesel fuel spill on a road
The presence of oil has significant social and environmental impacts, from accidents and routine activities such as seismic exploration, drilling, and generation of polluting wastes not produced by other alternative energies.
Extraction
Oil extraction is costly and sometimes environmentally damaging, although Dr. John Hunt of the Woods Hole Oceanographic Institution pointed out in a 1981 paper that over 70% of the reserves in the world are associated with visible macroseepages, and many oil fields are found due to natural seeps. Offshore exploration and extraction of oil disturbs the surrounding marine environment. Extraction may involve dredging, which stirs up the seabed, killing the sea plants that marine creatures need to survive. But at the same time, offshore oil platforms also form micro-habitats for marine creatures.
Oil spills
Crude oil and refined fuel spills from tanker ship accidents have damaged natural ecosystems in Alaska, the Galapagos Islands, France and many other places.
The quantity of oil spilled during accidents has ranged from a few hundred tons to several hundred thousand tons (Atlantic Empress, Amoco Cadiz...). Smaller spills have already proven to have a great impact on ecosystems, such as the Exxon Valdez oil spill
Oil spills at sea are generally much more damaging than those on land, since they can spread for hundreds of nautical miles in a thin oil slick which can cover beaches with a thin coating of oil. This can kill sea birds, mammals, shellfish and other organisms it coats. Oil spills on land are more readily containable if a makeshift earth dam can be rapidly bulldozed around the spill site before most of the oil escapes, and land animals can avoid the oil more easily.
Control of oil spills is difficult, requires ad hoc methods, and often a large amount of manpower (picture). The dropping of bombs and incendiary devices from aircraft on the Torrey Canyon wreck produced poor results; modern techniques would include pumping the oil from the wreck, like in the Prestige oil spill or the Erika oil spill.
Global warming
Burning oil releases carbon dioxide (CO2) into the atmosphere, which is credited with contributing to global warming. Per joule, oil produces 15% less CO2 than coal, but 30% more than natural gas. However, the unique role of oil as the main source of transportation fuel makes reducing its CO2 emissions a difficult problem. While large power plants can, in theory, eliminate their CO2 emissions by techniques such as carbon sequestering or even use them to increase oil production through enhanced oil recovery techniques, these amelioration strategies do not generally work for individual vehicles
Thursday, July 31, 2008
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